This is a 1 Figure lit discussion (1FLO) based on a Figure from a 2015 JACS article on synthesizing conductive MOFs. This LO introduces students to Metal-Organic Frameworks and focuses on characterization techniques and spectroscopy.
This literature discussion explores the physical structures, electronic structures, and spectroscopic characterization of several porphyrin-based metal-organic frameworks through discussion of “Iron and Porphyrin Metal−Organic Frameworks: Insight into Structural Diversity, Stability, and Porosity,” Fateeva et al. Cryst. Growth Des. 2015, 15, 1819-1826, http://dx.doi.org/doi:10.1021/cg501855k.
Students read two review articles and one research article on platinum-based cancer therapeutic agents. These articles compresentively discuss various aspects of these drug agents such as discovery, synthesis, mode of function. Students read the articles and use the knowledge on coordination chemistry (structure, reactivity, bonding, etc.) to explain the information included in the articles.
References:
From syllabus:
This set of questions is based on a single figure from Rountree et al. Inorg. Chem. 2019, 58, 6647. In this article (“Decoding Proton-Coupled Electron Transfer with Potential-pKa Diagrams”), Jillian Dempsey’s group from the University of North Carolina examined the mechanism by which a nickel-containing catalyst brings about the reduction of H+ to form H2 in non-aqueous solvent.
An introduction to the chemistry of inorganic compounds and materials. Descriptive chemistry of the elements. A survey of Crystal Field Theory, band theory, and various acid-base theories. Use of the chemical and scientific literature. Introduction to the seminar concept.
Modern theories of bonding and structure, spectroscopy, redox chemistry, and reaction mechanisms. Coordination compounds, organometallic clusters, and catalysis.
Fundamental topics in inorganic chemistry will be explored, among them: atomic theory and periodicity of the elements, bonding and properties of solid state materials, main group chemistry, structure and bonding of coordination compounds, and bio-inorganic systems. The laboratory component of the course will give students experience with a various laboratory techniques used in the synthesis and characterization of inorganic compounds.