Analyzing the Proposed Reaction Profile in “Changing the Charge: Electrostatic Effects in Pd-Catalyzed Cross-Coupling”
Description
This LO is a literature discussion based on one figure in Chan et. al.
Relating Ligand Field Theory to Nickel Complex Color
Description
This In-Class Activity is meant to follow up discussions of ligand field theory toward the end of MO theory including the effects of sigma donors, pi donors, and pi acceptors, and how it relates to absorption spectra and observed color of some transition metal complexes. Students have learned crystal field theory and the effects of geometry/symmetry on ∆, then we extend to LFT and how the chemistries of different ligands affect ∆.
Advanced Inorganic Chemistry
Description
CHEM 405 Advanced Inorganic Chemistry – 4 Credit Hours
VIPEr Fellows 2022 Workshop Favorites
The second cohort of VIPEr fellows pulled together learning objects that they've used and liked or want to try the next time they teach their inorganic courses.
Inorganic Chemistry
Description
The course will cover the elements of the periodic table that are omitted in general and organic chemistry, mainly the transition (d-block) metals.
Metal/Ligand Proton Tautomerism Facilitates Dinuclear H2 Reductive Elimination (Kuo)
Description
This LO was developed in 2022 as part of a collection celebrating the “Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists” Inorganic Chemistry special issue. Check out the editorial and issue here: Editorial Special Issue
The questions below refer to the following 2020 publication by Dr. Jonathan Kuo and Dr. Karen Goldberg
Metal-Ligand Multiple Bonds: The Discovery of “Double Nickel” (Hillhouse)
Description
This LO focuses on creating complexes with multiple bonds between late transition metals and nitrogen. The questions will guide students through Mindiola and Hillhouse's communication that details the synthesis and investigation of three-coordinate terminal amido and imido complexes of nickel. This communication is significant because it describes the synthesis and structural characterization of what became known as his "double nickel" complex, which contains a Ni-N double bond.
Substitution Chemistry in Odd-Electron Iron Group Carbonyl Complexes (D'Acchioli)
Description
This LO brings together organometallic chemistry, electrochemistry, and computational chemistry in a complete whole, and shows how these different expertises and techniques all can add to our understanding of a rich chemical system. It might be of particular interest in a class dominated by even-electron and diamagnetic chemistry to give students an understanding of how practitioners approach odd-electron, paramagnetic systems.
Discussion of "Dirhodium(II/II)/NiO Photocathode for Photoelectrocatalytic Hydrogen Evolution with Red Light" (Turro)
Description
This Learning Object is dedicated to Prof. Claudia Turro as part of the VIPEr LGBTQIAN+ LO collection created in celebration of Pride Month (Jun) 2022. Prof. Turro was featured in the April 2022 special virtual issue Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists (https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00729). Claudia holds a special place in my heart. I came out later in life, and she was incredibly supportive as I wrestled with my identity as a gay man.