Inorganic Chemistry
From syllabus:
From syllabus:
This is a collection of LOs that I used to teach a junior-senior seminar course on organometallics during Fall 2018 at Harvey Mudd College. There were a total of 9 students in the course. The Junior student (there was only one this year) was taking 2nd semester organic concurrently and had not takein inorganic (as is typical).
This set of questions is based on a single figure from Rountree et al. Inorg. Chem. 2019, 58, 6647. In this article (“Decoding Proton-Coupled Electron Transfer with Potential-pKa Diagrams”), Jillian Dempsey’s group from the University of North Carolina examined the mechanism by which a nickel-containing catalyst brings about the reduction of H+ to form H2 in non-aqueous solvent.
This experiment tasks students with preparing triphenylphosphine sulfide, and the corresponding I2 adduct, then characterizing these products using common instrumental methods. Students are asked to consider MOs and tie this to their Lewis bonding depiction for the final product. This discussion is supported by WebMO calculations and tied to the experimental data obtained by the student.
Theoretical and descriptive inorganic/bioinorganic chemistry. Examines molecular structure and other properties of crystals, coordination compounds, and organometallic compounds. Topics include the roles of metal complexes as acids and bases, in oxidation-reduction reactions, and in biochemical systems. Laboratory in which main group and transition metal compounds are synthesized and studied. This course counts towards the Writing Across the Curriculum requirement.
Modern theories of bonding and structure, spectroscopy, redox chemistry, and reaction mechanisms. Coordination compounds, organometallic clusters, and catalysis.
Surveys classical and contemporary approaches to the study of coordination compounds, solid-state chemistry and the chemistry of elements based on groups in the periodic table.
This second semester general chemistry course is a continuation of the Principles of Chemistry sequence that is recommended for science students. The focus of the course is the fundamentals of structure and bonding, with an emphasis on predicting reactivity.
CHEM 4654 (CRN: 10411) and the accompanying lab (CHEM 4654L) is worth 4 credit hours. CHEM 4654 covers atomic theory and spectroscopy, periodic properties, descriptive chemistry, inorganic structure and bonding, coordination chemistry, organometallic chemistry, symmetry and group theory. Students must be concurrently enrolled in CHEM 4654L (CRN: 10412).