This literature discussion focuses upon two journal articles by the Rebek group on the synthesis and host-guest chemistry observed with the "tennis ball."
The Rebek Laboratory homepage contains information on and molecular visualizations of a variety of host-guest systems developed by the research group over several decades. The theme behind this set of examples is the use of hydrogen-bonding to achieve self-assembly. Under the "Research" tab, one can find four videos with narration: an introduction to molecular assembly and three videos of specific examples of self-assembled host systems (the cavitand, the cylinder and the volleyball).
This in-class activity was designed for a Chemical Communications course with second-year students. It is the second part of a two-week segment in which students learn how to use ChemDraw (or similar drawing software to create digital drawings of molecules).
This course is composed of two components:
A. Lecture:
This set of slides was made for my Organometallics class based on questions about bridging hydrides and specifically the chromium molecule. I decided to make these slides to answer the questions, and do a DFT calc to show the MO's involved in bonding of the hydride.
This course is an introduction to the field of inorganic chemistry. The student is expected to be well-versed in the material covered in general chemistry, as this will serve as the foundation and launching point for the material to be covered this semester. The course will begin by examining the properties of the elements, and expand outward to consider chemical bonding and the electronic factors that govern metal reactivity. These factors include acid-base theory, thermodynamics, electrochemistry and redox, and coordination chemistry.
This course is designed to give an introduction to the concepts of electronic structure, bonding,
and reactivity in inorganic chemistry. The field is too vast to comprehensively cover every aspect in
a single semester, so this class will offer a qualitative overview of inorganic chemistry. Reading and
understanding scientific literature is an important skill for any scientist to have, whether you move
on to grad school, professional school, or the job market, so relevant literature articles will be
This Learning Object came to being sort of (In-)organically on the first day of my sophomore level intro to inorganic course. As I always do, I started the course with the IC Top 10 First Day Activity. (https://www.ionicviper.org/classactivity/ic-top-10-first-day-activity). One of the pieces of that In class activity asks students- novices at Inorganic Chemistry- to sort the articles from the Most Read Articles from Inorganic Chemistry into bins of the various subdisciplines of Inorganic Chemistry.
What is a foundations inorganic course? Here is a great description
This is a basic introduction to Enemark-Feltham that can be used in conjunction with any literature that has Iron nitrosyls in it. I made this as a follow up to the work that came ouf of the 2018 VIPEr workshop in UM-Dearborn.