Zeolite Synthesis
This lab was part of the materials science portion of my second-year inorganic chemistry course. Students synthesize a zeolite structure and grow a chemical garden as examples of silicate chemistry.
This lab was part of the materials science portion of my second-year inorganic chemistry course. Students synthesize a zeolite structure and grow a chemical garden as examples of silicate chemistry.
Students use a Java-based website to explore the faujasite zeolite structure. The activity questions guide them through identifying different atomic positions within the structure, and orienting the zeolite pores and "cages" relative to the crystal axes.
This lab handout and supplementary materials were developed based on a publication in the Journal of Chemical Education:
Berger, P.; Adelman, N.; Beckman, K.; Campbell, D.; Ellis, A.; Lisensky, G. Preparation and Properties of an Aqueous Ferrofluid. J. Chem. Educ. 1999, 76 (7), 943-48
I used this paper to illustrate several course concepts related to materials structure (crystal lattice structure, coordination number, crystal field theory and orbital splitting, symmetry, electronic spectra, allowed and forbidden transitions). This activity was paired with a laboratory experiment (see related VIPEr objects) in which students synthesized Prussian Blue, and gave students a really in-depth look at what was going on when they mixed those solutions together.
In this activity, the provided d orbital splitting patterns need to be matched with ligand geometries. Students are provided with the d orbital splitting diagrams for 6 ligand geometries (octahedral, trigonal bipyramidal, square pyramidal, tetrahedral, square planar, and linear). A web browser is used to view an animation (developed by Flick Coleman) which allows for the visualization of the relationship between the positions of the metal d orbitals and the ligands. Given this information, students should then be able to qualitatively rank the orbitals from highest to lowest energy.
I use this literature discussion in my second year inorganic class as a follow-up to a lab experiment where students synthesize Werner complexes and then (with much guidance) analyze their IR spectra using symmetry and group theory arguments. This paper provides an excellent example of how cobalt complexes are used in modern applications, and serves as a bridge to bioinorganic chemistry, which is a central feature later in the course.
Late in their junior year and into the first two months of their senior year, chemistry majors at Willamette write and submit a research proposal. Shortly before entering the lab for their thesis work, I lead this activity that takes place in our Senior Projects seminar class. The class meets one hour per week and we cover topics such as how to write an effective grant proposal, ethics in science, presenting data, etc., as well as this safety activity.
This learning object is designed to spark discussion and educate students taking an inorganic chemistry course about laboratory safety. It uses the article "Learning from UCLA" by Jyllian N. Kemsley (Chemical & Engineering News (2009), Vol. 87 Issue 31, pp.
This is a kinesthetic activity in which students must utilize knowledge of the σ-donating, π-donating and π-accepting ability of ligands in order to rank the ligands in the spectrochemical series. Students are each assigned a ligand on a card. Suggested ligands are I-, Br-, Cl-, F-, ONO-, NO2- OH-, H2O, pyridine, NH3, ethylenediamine, bipyridine, phenanthroline, PPh3, CN- and CO. Each student must evaluate the π-accepting, π-donating and σ-donating ability o