Introduction to Equilibrium and Aqueous Acids

Submitted by Adam Johnson / Harvey Mudd College on Sun, 05/15/2016 - 14:04
Description

Equilibrium reactions are those that are dynamic: the reaction can shift to form more reactants or more products depending on the physical or chemical conditions present. They were discovered and described empirically, but have a thermodynamic basis in the Gibbs Energy of the reaction. A reaction at equilibrium has both reactants and products present, and the rate of formation of products is equal to the rate of formation of reactants. A common application of equilibrium is the chemistry of aqueous acids. Acid strength is measured by the pH scale.

Water reclamation on the ISS: “Houston, we have a problem.”

Submitted by Adam Johnson / Harvey Mudd College on Sun, 05/15/2016 - 13:57
Description

Equilibrium reactions are those that are dynamic: the reaction can shift to form more reactants or more products depending on the physical or chemical conditions present. They were discovered and described empirically, but have a thermodynamic basis in the Gibbs Energy of the reaction. A reaction at equilibrium has both reactants and products present, and the rate of formation of products is equal to the rate of formation of reactants. A common application of equilibrium is the chemistry of aqueous acids. Acid strength is measured by the pH scale.

Energy Content of Fuels--Which fuel is "Best?"

Submitted by Adam Johnson / Harvey Mudd College on Sun, 05/15/2016 - 10:02
Description

There are many factors to consider when choosing a fuel. In this exercise, your group will work with a set of three different potential fuels and evaluate their performance in terms of price, energy density (per mole, per gram, and per volume) as well as in terms of CO2 emissions. You will then select which of your three fuels is the “best,” realizing that there are several possible considerations to select the “best” fuel. You will have to defend your choice, as well as your definition of “best!”

soapmaking activity

Submitted by Adam Johnson / Harvey Mudd College on Sat, 05/14/2016 - 22:36
Description

This in-class activity is designed to follow the linked lecture/demonstration on soapmaking. The soaps cure enough to be handled in 48 hours if kept warm, and the students can feel the difference in the canola/coconut oil soaps.

The calcuations go through the major reactions, functional groups, and physical properties of soap molecules, and ends with the calculation of molecular weight for a mixture of substances. This could be related to a later polymer unit.

soapmaking lecture/demo

Submitted by Adam Johnson / Harvey Mudd College on Sat, 05/14/2016 - 22:26
Description

This is a short presentation that outlines the major chemical reactions of soapmaking. Included are instructions for making two soaps, one from canola oil, the other from coconut oil. These two soaps have very different hardnesses, which can be explained by examining the structures of the oils. If you have never made soap before, it isn't that difficult, but it does use concentrated NaOH so is very caustic before the reaction is done. The linked websited have good instructions for soapmaking as well.

Shape & Polarity Review with Clickers

Submitted by Jim Kirby / Quinnipiac University on Tue, 07/07/2015 - 00:01
Description

A set of questions to be used in General or Introductory Inorganic Chemistry as a review or “quiz” of shapes and polarities.

Peer Review - How does it work?: A literature discussion with a focus on scientific communication

Submitted by Mike Norris / University of Richmond on Thu, 07/02/2015 - 20:21
Description

This learning object is based on discussion of the literature, but it follows a paper through the peer review process.  Students first read the original submitted draft of a paper to ChemComm that looks at photochemical reduction of methyl viologen using CdSe quantum dots.  There are several important themes relating to solar energy storage and the techniques discussed, UV/vis, SEM, TEM, electrochemistry, and catalysis, can be used for students in inorganic chemistry.

Kinetics of electrocatalytic reduction of carbon dioxide by Mn catalysts containing bulky bipyridine ligands

Submitted by Kathleen Field / WGU on Thu, 07/02/2015 - 17:23
Description

This question set has students examine the kinetics of the electrocatalytic reduction of CO2 to CO described in Sampson, D.L.; Nguygen, D., Grice, K.A.; Moore, C.E.; Rheingold, A.L.; Kubiak, C.P. Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide:  Eliminating Dimerization and Altering Catalysis.  J. Am. Chem. Soc. 2014, 136, 5460-5471. 

Analyzing a journal article for basic themes, roles of authors, and the scientific method

Submitted by Darren Achey / Kutztown University on Thu, 07/02/2015 - 15:03
Description

This literature discussion is meant to give students an understanding of both the key concept-driven and more “meta” information of a literature paper.  Students will use Jillian Dempsey’s paper, “Electrochemical hydrogenation of a homogeneous nickel complex to form a surface-adsorbed hydrogen-evolving species,” to investigate paper authorship, how the scientific method is used in research, and how to understand the important findings of a research article.

 

Reference: Chem. Commun., 2015, 51, 5290-5293

DOI:10.1039/C4CC08662G

 

Chemistry Infographics from Compound Interest

Submitted by Darren Achey / Kutztown University on Tue, 06/30/2015 - 14:48
Description

Compound Interest is a website that creates infographics for chemistry related events and items.  Specific examples of inorganic chemistry infographics include showing how the metal content in colored glass gives the glass its characteristic color, how the lighting of a match works with the conversion of red phosphorus to white phosphorus, and the various colors that transition metals can have in different oxidation states in water, among many other examples.