Porphyrin-Based Metal-Organic Frameworks

Submitted by Amanda Bowman / Colorado College on Thu, 06/27/2019 - 15:29
Description

This literature discussion explores the physical structures, electronic structures, and spectroscopic characterization of several porphyrin-based metal-organic frameworks through discussion of “Iron and Porphyrin Metal−Organic Frameworks: Insight into Structural Diversity, Stability, and Porosity,” Fateeva et al. Cryst. Growth Des. 2015, 15, 1819-1826, http://dx.doi.org/doi:10.1021/cg501855k.

Comprehensive literature reading assignment on platinum-based anticancer agents

Submitted by Todsapon T. / University of Evansville on Sun, 06/09/2019 - 16:40
Description

Students read two review articles and one research article on platinum-based cancer therapeutic agents.  These articles compresentively discuss various aspects of these drug agents such as discovery, synthesis, mode of function.  Students read the articles and use the knowledge on coordination chemistry (structure, reactivity, bonding, etc.) to explain the information included in the articles. 

 

References:

VIPEr Fellows 2019 Workshop Favorites

Submitted by Barbara Reisner / James Madison University on Sat, 06/08/2019 - 16:41

During our first fellows workshop, the first cohort of VIPEr fellows pulled together learning objects that they've used and liked or want to try the next time they teach their inorganic courses.

Guided reading and in-class discussion questions for "High-Spin Square-Planar Co(II) and Fe(II) Complexes and Reasons for Their Electronic Structure"
Description

Guided reading and in-class discussion questions for "High-Spin Square-Planar Co(II) and Fe(II) Complexes and Reasons for Their Electronic Structure."

John Miecznikowski / Fairfield University Thu, 06/06/2019 - 15:46

The Synthesis and Electronic Structure of [NiX4]2- Complexes and the Role of Crown Ethers in Inorganic Synthesis

Submitted by Wes Farrell / United States Naval Academy on Thu, 06/06/2019 - 15:05
Description

This literature discussion aims to have students in an advanced inorganic chemistry course interpret reaction schemes and electronic spectra, relate chemical formulae to molecular structure, and gain an understanding of how inorganic synthesis is planned and executed.  Students should gain an understanding of how counterions and crown ethers affect structure. Question 7 may be expanded to ask students to why pi-donor ability affects ligand field splitting, or as an introfuction to this topic.

An associated 1FLO based on this paper is linked in the related content.

 

Zinc-Zinc Bonds (Expanded and Updated)

Submitted by Wes Farrell / United States Naval Academy on Wed, 06/05/2019 - 11:42
Description

This paper in Science reports the synthesis of decamethyldizincocene, a stable compound of Zn(I) with a zinc-zinc bond. In the original LO, the title compound and the starting material, bis(pentamethylcyclopentadienyl)zinc, offer a nice link to metallocene chemistry, electron counting, and different modes of binding of cyclopentadienyl rings as well as more advanced discussions of MO diagrams.

Quadruple Bond Acrobatics

Submitted by Lori Watson / Earlham College on Tue, 05/28/2019 - 14:40
Description

Four pairs of students represent quadruple bonding in metal complexes by "forming bonds" with a variety of physical methods involving actions like facing each other while holding hands (sigma bond), touch hands and feet of their partner "above and below" the plane (two pi bonds), touching hands and feet while facing each other (delta bond).  This results in a "Twister"-like pile of students resembling the quadruple bonding interaction