This study guide/question set will help a student navigate through the related research paper and test the student's understanding on the effects of hydrogen bonding in synthetic Cu-O2 adducts in the realm of bioinorganic model chemistry.

This literature discussion highlights recent research from the Rosenzweig group that probes the structural and spectroscopic properties of a newly discovered, atypical Cu_A site located in a PmoD protein in a new class of methane-oxidizing bacteria.

Various topics ranging from coordination chemistry, electrochemistry, solid state chemistry and point group and symmetry are discussed from the JACS article published by Smaranda C. Marinescu and her co-workers.  The article describes the conversion of CO₂ to CO by using cobalt aminopyridine macrocycle catalysts.

This is one of a collection of learning objects developed to honor the 2021 ACS Award Winners in inorganic chemistry.  Marinella Mazzanti from the Swiss Federal Institute of Technology was awarded the F. Albert Cotton Award in Synthetic Inorganic Chemistry for her outstanding accomplishments in uranium and lanthanide chemistry, including the stabilization of unusual oxidation states and multimetallic cluster synthesis and small-molecule activation. In this paper photoredox chemistry is used to synthesize a uranium (VI) nitride.

The LO focuses upon classic articles describing the synthesis and characterization of the first "texaphyrin" compounds.

This LO is part of a special VIPEr collection honoring the 2021 ACS National Award recipients in the field of inorganic chemistry. Jonathan L. Sessler was the recipient of the Ronald Breslow Award for Achievement in Biomimetic Chemistry for the discovery of expanded porphyrins, molecular recognition via base-pairing, pyrrole-based anion binding, and demonstrating the power of this biomimetic chemistry in drug discovery.

The discussion covers a 2021 publication by the Chirik group (Nature Chemistry, 2021, DOI: 10.1038/s41557-020-00614-w) which details the discovery of a new way to polymerize butadiene through iron-catalyzed [2+2] cycloadd

In this literature discussion, students are asked to explore the chemistry behind a eta-1 to eta-2 linkage photoisomer of sulfur dioxide bound to pentammine osmium. There are questions that tie to chemical structure and the nature of the two bonding modes of the ligand as well as an examination of the spectroscopic properties of the complex in the solid state. Two of the questions ask students to draw some conclusions based on their knowledge of periodic trends and the sigma donor ability of ligands.