Metal/Ligand Proton Tautomerism Facilitates Dinuclear H2 Reductive Elimination (Kuo)

Submitted by Kyle Grice / DePaul University on Tue, 06/07/2022 - 11:11
Description

This LO was developed in 2022 as part of a collection celebrating the “Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists” Inorganic Chemistry special issue. Check out the editorial and issue here: Editorial  Special Issue

The questions below refer to the following 2020 publication by Dr. Jonathan Kuo and Dr. Karen Goldberg

Metal-Ligand Multiple Bonds: The Discovery of “Double Nickel” (Hillhouse)

Submitted by Anthony L. Fernandez / Merrimack College on Wed, 06/01/2022 - 00:52
Description

This LO focuses on creating complexes with multiple bonds between late transition metals and nitrogen. The questions will guide students through Mindiola and Hillhouse's communication that details the synthesis and investigation of three-coordinate terminal amido and imido complexes of nickel. This communication is significant because it describes the synthesis and structural characterization of what became known as his "double nickel" complex, which contains a Ni-N double bond.  

Summer SLiThErs

Submitted by Chip Nataro / Lafayette College on Mon, 05/23/2022 - 07:49

As we head into June, it is time to be thinking about upcoming SLiThEr events. While the entire schedule is not quite set yet, I can provide a brief glimpse into what could be coming up this summer.

Literature 3-2-1

Submitted by James F. Dunne / Central College on Sun, 05/22/2022 - 14:24
Description

This is a general assignment given prior to discussing a paper in class.  Students are asked to read a particular literature paper, and then fill out the template giving the citation information of the paper and: three (3) new things they learned from the paper, two (2) questions that reading the paper raised for them or left unanswered, and one (1) reference cited by the paper that the student thinks is worth reading and why.  The assignment helps seed the discussion prior to class, and gives the instructor some information about specific details to discuss to fill in gaps in the students'

Discussion of "Dirhodium(II/II)/NiO Photocathode for Photoelectrocatalytic Hydrogen Evolution with Red Light" (Turro)

Submitted by Jason D'Acchioli / University of Wisconsin-Stevens Point on Sat, 05/21/2022 - 12:13
Description

This Learning Object is dedicated to Prof. Claudia Turro as part of the VIPEr LGBTQIAN+ LO collection created in celebration of Pride Month (Jun) 2022. Prof. Turro was featured in the April 2022 special virtual issue Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists (https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00729). Claudia holds a special place in my heart. I came out later in life, and she was incredibly supportive as I wrestled with my identity as a gay man.

Mechanistic Study of Competitive sp3-sp3 and sp2-sp3 Carbon-Carbon Reductive Elimination from a Platinum(IV) Center and the Isolation of a C-C Agostic Complex (Williams)

Submitted by Shirley Lin / United States Naval Academy on Fri, 05/20/2022 - 08:09
Description

This literature discussion focuses on a J. Am. Chem. Soc. communication that describes a series of Pt complexes that exhibit competitive reductive elimination reactions to form either an sp2-sp3 bond or an sp3-sp3 bond. One of the complexes also contains a C-C agostic interaction with the metal. The questions are written to be addressed by students in a foundation-level inorganic course.