In this literature discussion, students use a paper from the literature to explore the synthesis, structure, characterization (powder XRD, EDS and TEM) and energetics associated with the production of a metastable wurtzite CoS phase. Students also are asked define key terms and acronyms used in the paper; identify the goal of the experiments and determine if the authors met their goal. They examine the fundamental concepts around the key crystal structures available.
Preserving Both Anion and Cation Sublattice Features during a Nanocrystal Cation-Exchange Reaction: Synthesis of a Metastable Wurtzite-Type CoS and MnS
Powell, A.E., Hodges J.M., Schaak, R.E. J. Am. Chem. Soc. 2016, 138, 471-474.
There is an in class activitiy specifically written for this paper.
In answering these questions, a student will be able to…
define important scientific terms and acronyms associated with the paper;
describe the rocksalt, NiAs, wurtzite, and zinc blende in terms of anion packing and cation coordination;
differentiate between the structure types described in the paper;
explain the difference between thermodynamically stable and metastable phases and relate it to a free energy diagram; and
describe the structural and composition information obtained from EDS, powder XRD, and TEM experiments.
This learning object was created at the 2017 IONiC Workshop on VIPEr and Literature Discussion. It has not yet been used in class.